In by admin

Name Ms. Hang Lu
Organization or Institution University of Florida
Presentation Type Poster
Topic Inorganic Chemistry
Title

Investigation of Pt(II) precursors for electron beam-induced deposition of Pt nanostructures

Author(s)

Hang Lu1, Julie A. Spencer2, Filipe Ferreira da Silva4, Oddur Ingólfsson3, Howard Fairbrother2, Lisa McElwee-White1

Author Institution(s)

1. Department of Chemistry, University of Florida, Gainesville, FL, United States.
2. Johns Hopkins University, Baltimore, MD, United States.
3. Department of Chemistry, University of Iceland, Reykjavik, Iceland.
4. Departamento de Física, Universidade NOVA de Lisboa, Caparica, Portugal.

Abstract

To enable the electron beam-induced deposition (EBID) of Pt nanostructures, Pt(II) precursors have been designed and synthesized specifically for EBID.  The electron-induced reactions of those precursors have been investigated under ultrahigh vacuum (UHV) surface science conditions and gas phase electron-molecule interactions have also been studied.  Compared with traditional commercially available Pt precursors, cis-Pt(CO)2Cl2 has been found to produce high metal content deposits upon loss of both CO and Cl ligands.  These results inform the design of additional EBID precursors.